You may want to check this video by George Peirson . . .
With the Adobe Color Wheel you can create pleasing color themes using one of many different color models. In this Adobe Color Wheel how to use video I will show you the different color theme models, how to balance the color, pick the colors you want, save them as a swatch set to the online library, and then export the colors as a swatch set which can be used in Photoshop Elements. I then show you how to import the color swatch set into Photoshop Elements and how to save the color swatch for future use.